Catalog Search Results
Author
Series
Great Courses volume 23
Language
English
Description
Apply the physics of moving bodies to the countless particles comprising a gas. Observe how Graham's law links the mass of gas particles to the rate at which they escape through a small aperture, a process known as effusion. See how this technique was used to enrich uranium for the first atomic weapons.
Author
Series
Great Courses volume 36
Language
English
Description
In the previous lecture, you delved into strong acids and bases - those that ionize completely in solution. In this lecture, survey weak acids and bases, zeroing in on why they only partially ionize. Practice techniques for calculating their properties and concentrations in various solutions.
Author
Series
Great Courses volume 6
Language
English
Description
Make sense of a crucial concept in organic chemistry: the handedness of molecules, or, as chemists call it, "chirality." Topics include the definition of chiral tetrahedral centers; the creation of stereoisomer sets via inversion of handedness; and intriguing examples of stereoisomers (including enantiomers and double-bonded stereoisomers) and their unique chiral centers.
Author
Series
Great Courses volume 16
Language
English
Description
Consider how atoms and molecules can create, consume, and transport the most vital commodity in the universe: energy. Practice calculating energy changes in reactions, explore the concept of enthalpy (the total heat content of a system), and learn how chemists use a device called a calorimeter.
Author
Series
Great Courses volume 5
Language
English
Description
Peel back the layers of the atom to investigate what's inside. Observe how electrons, protons, and neutrons are distributed, how they give an atom its identity, and how they affect its electrical charge and atomic mass. Discover the meaning of terms such as isotope, anion, and cation.
Author
Series
Great Courses volume 31
Language
English
Description
In this final lecture on spectroscopic techniques, discover the importance of modern NMR spectrometers, which use superconducting magnets and radio receivers to collect spectra with more speed and precision (and in different ways) than other techniques. Also, get an intriguing lesson in the human element - and limitations - involved in spectroscopy.
Author
Series
Great Courses volume 22
Language
English
Description
Start taking a more biologically oriented look at the foundations of organic chemistry by investigating compounds known as carbohydrates. Examine Fischer projections of their two main classes, aldoses and ketoses; learn how cyclic sugars help create disaccharides and polysaccharides used in everything from fruit preserves to body armor; and more.
Author
Series
Great Courses volume 48
Language
English
Description
Hydrocarbons contain only hydrogen and carbon atoms. See how some of the hydrogen atoms can be replaced with new elements and groups of elements to create compounds with new properties. These heteroatoms and functional groups form virtually unlimited combinations of organic molecules.
Author
Series
Great Courses volume 17
Language
English
Description
In 1840, chemist Germain Hess theorized that total heat change in a chemical reaction is equal to the sum of the heat changes of its individual steps. Study the implications of this principle, known as Hess's law. In the process, learn about heat of formation.
Author
Series
Great Courses volume 34
Language
English
Description
Discover how solubility makes for an extremely effective tool for isolating non-volatile organic compounds through liquid-liquid and solid-liquid extractions (part of a larger phenomenon known as partitioning). As you delve into these processes, you'll learn one way to better understand extractions: making a perfect cup of tea.
Author
Series
Great Courses volume 4
Language
English
Description
You've learned how to depict molecules as they exist at a single point in time. How about as time passes? The answer: much like a cartoonist. Here, learn about this scientific art form, including writing reaction schemes, expanding them into elementary steps, using curved arrows to chart molecular progress, and more.
Author
Series
Great Courses volume 2
Language
English
Description
Chemists have convenient units for dealing with matter at the atomic scale. In this lecture, learn the origin and relative size of the angstrom to measure length, as well as the atomic mass unit, the mole for measuring quantity and the Kelvin scale for temperature.
Author
Series
Great Courses volume 18
Language
English
Description
Now turn to entropy, which is a measure of disorder. According to the second law of thermodynamics, the entropy of closed systems always increases. See how this change can be calculated in chemical reactions by using the absolute entropy table.
Author
Series
Great Courses volume 30
Language
English
Description
Starting with a classic experiment called the elephant's toothpaste, begin your investigation of reaction rates. Learn to express rates mathematically and understand the importance of rate order, which is related to the powers of the concentrations. Extend these ideas to half-life equations, which are vital for dating geologic processes and archaeological artifacts.
Author
Series
Great Courses volume 19
Language
English
Description
Enthalpy and entropy are contrasting quantities. However, they are combined in the free energy equation, discovered by chemist J. Willard Gibbs, which predicts whether a reaction will take place spontaneously. Probe the difference between reactions that are endothermic (requiring heat) and exothermic (releasing heat).
Author
Series
Great Courses volume 35
Language
English
Description
Chromatography - in which partitioning between stationary and mobile phases leads to predictable rates of movement for compounds - is one of the most powerful separation techniques ever developed. And, when done properly, it allows chemists to isolate almost anything they can imagine. Witness a technique at the core of Professor Davis's laboratory experience.
Author
Series
Great Courses volume 10
Language
English
Description
Working at the turn of the 20th century, chemist Gilbert N. Lewis devised a simple method for depicting the essential blueprint of a molecule's structure. Learn how to draw Lewis structures, and use this technique to explore such concepts as formal charge and resonance.
Author
Series
Great Courses volume 10
Language
English
Description
Explore alkyl halides, hydrocarbons where one or more hydrogen atoms are replaced by a halogen atom. You'll examine how larger halogen atoms decrease the volatility of alkyl halides compared to their alkane counterparts (which radically changed the science of refrigeration). You'll also learn about the reactivity of alkyl halides and the phenomenon of carbocation rearrangements.
Author
Series
Great Courses volume 25
Language
English
Description
Solids are characterized by a defined volume and shape, created by close packing of atoms, ions, or molecules. Focus on how packing is very regular in crystalline solids, which display lattice geometries. In particular, study the structure and properties of metals and alloys.
Author
Series
Great Courses volume 24
Language
English
Description
Now turn to liquids, which have a more complicated behavior than gases. The same intermolecular forces apply to both, but at much closer range for liquids. Explore the resulting properties, including viscosity, volatility, incompressibility, and miscibility. Also consider applications of these qualities.
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